January 12, 2024

Covalent Bond

Sigma (σ) and Pi (π) Bond
Covalent Bond The bond which is formed by mutual sharing of electrons is called a covalent bond.


Type: 1.Sigma Bond
2. Pi bond
Both Sigma and pi bonds are formed by overlapping of the s and p orbital.
The shape of s orbital: It is of a spherical shape.


The spherical shape of S orbital


Nodes between S orbital with Principal quantum number

P orbital: It is of dumbbell shape


P orbital

Sigma Bond
This is covalent which is formed by axial overlapping of S-S, S-P, and P-P orbital.

s- s
overlapping Eg. In hydrogen, this type of overlapping takes place to form a sigma bond.


S-p overlapping
e.g. methane


s-p overlapping and p-p overlapping
e.g ethane


Pi (π) bond: It is the covalent bond which is formed in sided ways overlapping of p- p orbital.It is present in a compound containing a double or triple bond


e.g a) Ethene


b) ethyne


c) Benzene ( orbital picture)

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